2-AMINO-4'-BROMOBENZOPHENONE


  • CAS 1140-17-6
  • Purity 99%
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Offer Chemical Raw Material 2-AMINO-4'-BROMOBENZOPHENONE 1140-17-6 In Stock

  • Molecular Formula: C13H10 Br N O
  • Molecular Weight: 276.132
  • Melting Point: 103-110oC 
  • Boiling Point: 432.5±25.0 °C(Predicted) 
  • PKA: -0.36±0.10(Predicted) 
  • Flash Point: 215.4oC 
  • PSA: 43.09000 
  • Density: 1.484±0.06 g/cm3 (20 ºC 760 Torr) 
  • LogP: 3.84350 

1140-17-6 Relevant articles

Palladium-catalyzed direct addition of 2-Aminobenzonitriles to sodium arylsulfinates: Synthesis of o-Aminobenzophenones

Chen, Jiuxi,Li, Jianjun,Su, Weike

, p. 6439 - 6449 (2014)

The first example of the palladium-catal...

Design, synthesis, crystal structures, and photophysical properties of tetraphenylethene-based quinoline derivatives

Zhu, Xiaolin,Wang, Danfeng,Huang, Hai,Zhang, Xueqiong,Wang, Shifan,Liu, Rui,Zhu, Hongjun

, (2019)

The incorporation of aggregation-induced...

Benzene type liquid crystal compound and preparation method thereof

-

Paragraph 0100; 0111-0114; 0142; 0152-0154, (2021/09/29)

The invention relates to the technical f...

Experimental and Computational Studies on Cp*CyRh(III)/KOPiv-Catalyzed Intramolecular Dehydrogenative Cross-Couplings for Building Eight-Membered Sultam/Lactam Frameworks

Li, Liping,Gao, Hui,Sun, Ming,Zhou, Zhi,Yi, Wei

supporting information, p. 5473 - 5478 (2020/07/14)

Described herein is an unusual Cp*CyRh(I...

One-Pot Synthesis of Spirocyclopenta[ a]indene Derivatives via a Cascade Ring Expansion and Intramolecular Friedel-Crafts-Type Cyclization

Li, Quanzhe,Liu, Jiaxin,Wei, Yin,Shi, Min

, p. 2438 - 2455 (2020/01/31)

A one-pot efficient synthetic approach f...

Method for catalytically synthesizing Bronuck intermediate 2-amino-4'-bromo-benzophenone

-

Paragraph 0052; 0054; 0055; 0056; 0057; 0058-0089, (2019/04/26)

The invention relates to a method for ca...

1140-17-6 Process route

(2-nitrophenyl)(4-bromophenyl)methanone
861781-61-5

(2-nitrophenyl)(4-bromophenyl)methanone

2-amino-4'-bromobenzophenone
1140-17-6

2-amino-4'-bromobenzophenone

Conditions
Conditions Yield
With hydrogenchloride; iron; In ethanol; water; for 1h; Reflux;
90%
With hydrogenchloride; water; iron; In ethanol; for 1h; Reflux;
90%
With iron; acetic acid; In water; ethyl acetate; for 2h; Concentration; Time; Reflux;
90%
With iron; acetic acid; In water; ethyl acetate; for 1.5h; Inert atmosphere; Reflux;
77.9%
With hydrogenchloride; iron; In ethanol; water; at 80 ℃; for 2h;
4-Bromophenylboronic acid
5467-74-3

4-Bromophenylboronic acid

anthranilic acid nitrile
1885-29-6

anthranilic acid nitrile

2-amino-4'-bromobenzophenone
1140-17-6

2-amino-4'-bromobenzophenone

Conditions
Conditions Yield
With 1,2-bis(diphenylphosphino)ethane nickel(II) chloride; trifluoroacetic acid; In 1,4-dioxane; water; at 20 - 120 ℃; for 12h; Reagent/catalyst; Solvent;
86.8%
With 5,5'-dimethyl-2,2'-bipyridine; methanesulfonic acid; palladium(II) trifluoroacetate; water; In 2-methyltetrahydrofuran; at 80 ℃; for 36h; Schlenk technique;
76%
With [2,2]bipyridinyl; palladium(II) trifluoroacetate; In tetrahydrofuran; water; at 80 ℃;

1140-17-6 Upstream products

  • 2059-99-6
    2059-99-6

    2-(4-bromo-benzoyl)-benzoic acid amide

  • 118667-16-6
    118667-16-6

    4-bromo-benzophenone-(E )-oxime

  • 108-86-1
    108-86-1

    bromobenzene

  • 42840-02-8
    42840-02-8

    2-(Toluene-4-sulfonylamino)-benzoyl chloride

1140-17-6 Downstream products

  • 102703-55-9
    102703-55-9

    N -[2-(4-bromo-benzoyl)-phenyl]-phthalimide

  • 37892-44-7
    37892-44-7

    2-azido-4'-bromo-benzophenone

  • 500870-79-1
    500870-79-1

    2-N-(4-methylsulfonylbenzoyl)-amide-4'-bromo-benzophenone

  • 500870-80-4
    500870-80-4

    2-N-(4-aminosulfonylbenzoyl)-amide-4'-bromo-benzophenone

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